TS-059305 — A novel method in which nucleophilic transition metal hydroxide groups are generated at the internal pore surfaces of MOFs to facilitate selective gas-phase CO2 fixation at low pressures via formation of metal bicarbonate species.
Metal-organic frameworks (MOFs) are porous polymers constructed by self-assembly of organic and inorganic components. They have been extensively studied for gas storage and separation applications, and post-combustion CO2 capture under flue gas conditions has been a particularly intense area of st…