Combustion Looping Using Chemical Oxygen Carriers

A two-stage process that can utilize a number of solid, liquid, or gaseous carbon-based fuels to produce hydrogen gas

The Need

Hydrogen gas can be produced from many different feedstocks, such as natural gas, biomass, or water, using a number of different techniques, such as steam methane reformation (SMR). Hydrogen production from coal gasification and manufacturing of hydrogen by the reduction of steam using a metal species are currently established technologies. However, despite significant research in this area, an economically viable process for producing large amounts of relatively pure hydrogen gas has not been defined.

The Technology

Researchers at the The Ohio State University, led by Dr. Liang-Shih Fan, created a two-stage process that can utilize a number of solid, liquid, or gaseous carbon-based fuels to produce hydrogen gas. Porous composite particles containing a suitable metal oxide provide both large surface area for the redox reactions to take place and the ability to survive numerous processing cycles.

Commercial Applications

  • Coal power plants
  • Biomass production industries
  • Waste disposal plants
  • Automotive fuel cells

Benefits/Advantages

  • When used by coal power plants, the process will capture 100% of carbon emissions
  • Coal fed into the chemical looping machinery will be processed about twice as efficiently as conventional methods
  • The increases in efficiencies will allow industries to comply with EPA regulations more easily
  • In the automotive application, it may make hydrogen fuel cell cars more economically feasible

Patents

Patent # Title Country
102186955 Conversion of Carbonaceous Fuels Into Carbon Free Energy Carriers China
2737946 Conversion of Carbonaceous Fuels Into Carbon Free Energy Carriers Canada
7767191 Combustion Looping Using Composite Oxygen Carriers United States of America
7767191 Combustion Looping Using Composite Oxygen Carriers United States of America
8877147 Conversion of Carbonaceous Fuels Into Carbon Free Energy Carriers United States of America
I447329 Conversion of Carbonaceous Fuels Into Carbon Free Energy Carriers Taiwan
2406545 Conversion of Carbonaceous Fuels into Carbon Free Energy Carriers Europe
9376318 Conversion of carbonaceous fuels into carbon free energy carriers United States of America
10081772 Conversion of Carbonaceous Fuels into Carbon Free Energy Carriers United States of America
2406545 Conversion of Carbonaceous Fuels into Carbon Free Energy Carriers Germany
2406545 Conversion of Carbonaceous Fuels into Carbon Free Energy Carriers France
2406545 Conversion of Carbonaceous Fuels into Carbon Free Energy Carriers Spain
2406545 Conversion of Carbonaceous Fuels into Carbon Free Energy Carriers United Kingdom
2406545 Conversion of Carbonaceous Fuels into Carbon Free Energy Carriers Italy

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